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The following example uses a very simple scene. It contains five chairs , and a light source , and in a studio type environment. Each chair has a V-Ray Override material assigned, but only the Base Material is active. The rendered chairs are the same in their diffuse colors and reflections.

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Now each of the chairs has a different material assigned in their Override Reflection Material. The first one has a green diffuse color, the second one has black, the third one has blue, the fourth - purple, and the fifth has a red diffuse color. V-Ray uses those materials , when the objects are seen in reflections. In our project, the environment is actually a reflective surface, so the chairs are being reflected. On the other hand, you can also notice that the base material of the chairs is also reflective (Fresnel type), and the fourth chair is seen with its Override Reflection material in the middle chair.

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