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The AppSDK shipping with V-Ray for Maya comes only with the Python binding that matches the one V-Ray for Maya is built for. Thus, the Python 3 builds only have AppSDK with Python 3 binding, and the Python 2 builds only have AppSDK with Python 2 binding.
For full documentation of V-Ray Application SDK, please refer to V-Ray Application SDK.
To download SDK samples and sample scenes, you can download and unpack the official V-Ray App SDK build that contains them. Once installed, by default they reside in Program Files > Chaos Group > V-Ray > AppSDK > examples and Program Files > Chaos Group > V-Ray > AppSDK > scenes.